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| 2026, Vol. 43,No. 3 Published:25 August 2026 |
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Advances in Waste Sulfuric Acid Cracking and
Regeneration Technologies: Dry Process, Wet Process and Dry-wet Coupling
Process
Bai Zhishan, Li Shiwei
2026, 43 (3):
1-8.
DOI: 10.3969/j.issn.1005-8168.2026.03.001
The by-product
waste acid from sulfuric acid alkylation unit has a complex composition and
strong corrosiveness, making its efficient regeneration crucial for reducing
environmental treatment burdens and enabling sulfur resource recycling. Waste
acid cracking and regeneration technologies have developed into two main routes,
i.e., dry process and wet process, and are gradually evolving toward multi-unit
coupling and integrated treatment of various sulfur-containing materials. The
dry process can stably produce concentrated sulfuric acid with a mass fraction above
98%, but suffers from long process flow, high investment and energy
consumption, and wastewater generation. In contrast, the wet process features
compact process flow, efficient waste heat recovery, and zero wastewater
discharge; however, it faces challenges such as insufficient removal of fine
particulates, system clogging, and fluctuating product acid concentration. Therefore, balancing the stable production of high-concentration
sulfuric acid with the low energy consumption and low emissions of the unit has
become the core challenge in upgrading waste acid regeneration technology. To
address these issues, this paper focuses on reviewing two new technologies,
i.e., dry-wet coupling process and hydrogen sulfide - waste acid cracking and regeneration
combined process. The former integrates dynamic wave scrubbing, coalescing
demisting, steam reheating, and dry air condensation to achieve synergistic process
gas purification, moisture control, and energy utilization. The latter enables
coordinated treatment of waste acid and sulfur-containing materials such as
hydrogen sulfide through acid gas heating, merging of two furnace gas streams,
and sharing conversion-absorption system. Engineering operation results show that the dry-wet coupling process
achieves an overall dust removal efficiency of up to 99.9%, produces sulfuric
acid with a mass fraction exceeding 98%, and improves waste heat recovery efficiency
by over 20%. The hydrogen sulfide - waste acid cracking and regeneration combined
unit can be operated stably within a wide load range, and the waste acid
treatment capacity and operation flexibility can be improved by adopting acid
gas heating and sharing conversion-absorption system. This paper further
compares the applicable scenarios, technical bottlenecks, and engineering
performance of different technical routes, providing theoretical basis and
engineering reference for selecting waste acid regeneration schemes,
retrofitting existing units, and promoting the integrated utilization of
multiple sulfur-containing materials.
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Comparison of Crack Calculation for Water Tanks Based
on Chinese, American and Saudi Arabian Standards
Huang Yalan
2026, 43 (3):
9-13.
DOI: 10.3969/j.issn.1005-8168.2026.03.002
This paper lists the calculation formulas for crack width of concrete
water tanks in Chinese standards GB/T 50010-2010 Code for Design of Concrete Structures,
GB 50069-2002 Structural Design Code for
Special Structures of Water Supply and Waste Water Engineering, American standard
ACI 224R-01, and Saudi Arabian code SBC 304-AR/CR-2018, respectively. A
comparative analysis of the differences in parameter values adopted by various
national standards in calculating crack width is conducted, and the crack width
limits under different environmental categories and exposure conditions are
presented. Taking a project in Saudi Arabia as the example, this paper compares
the strictness of these national standards in crack width calculation, and
summarizes the crack control strategies and implementation key points of these
countries from the perspectives of material selection and construction technology,
aiming to provide reliable technical reference for the structural design of
pool structures, the refined management and control of cracks, and the collaborative
verification of multiple national standards in overseas engineering projects.
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Discussion on Planning and Design of Front Plant Area in
Petrochemical Projects
LI Wei
2026, 43 (3):
14-17.
DOI: 10.3969/j.issn.1005-8168.2026.03.003
This paper
systematically explores the principles and practical strategies for the planning
and design of front plant area in petrochemical projects. Unlike the design of urban
technology parks that emphasize visual impact, the design of front plant area
in petrochemical projects primarily adheres to the core industrial design logic
of "form follows function", aiming to create a simple, practical,
efficient, and harmonious architectural image and spatial environment while
meeting core functional requirements. Drawing on engineering experience, this
paper focuses on key aspects such as overall layout, functional organization,
traffic flow, safety measures, and landscape design in the front plant area.
The goal is to develop a set of planning and design methods suitable for this
specific type of area, providing reference for the optimized design of similar
projects.
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Techno-Economic Analysis of Hydrogen Recovery from PSA
Desorptioni Gas in a Refining and Petrochemical Enterprise
Dai Pengcheng, Tang Shuai, Zhang Huaisen, Zhang Zhijun, Cao Bo
2026, 43 (3):
18-24.
DOI: 10.3969/j.issn.1005-8168.2026.03.004
Hydrogen is an
indispensable feedstock for petrochemical production. To recover hydrogen from
CO-containing desorption gas and enhance the plant-wide hydrogen utilization
efficiency, the process flow of the existing pressure swing adsorption (PSA) unit
for CH4 impurity removal was to be optimized. Based on the
fundamental PSA theory and the current operational data, the unit's CO
adsorption capacity was calculated, and the theoretical calculation formula for
the adsorption time of the modified unit was derived. The results technically
demonstrated the unit's capability to process CO-containing gas sources. An
analysis of the additional costs and economic benefits after the modification shows
that the modified unit could recover 17.9 million kg of hydrogen annually,
generating a direct economic benefit of 40.9147 million yuan for the
enterprise. The results demonstrate that this modification scheme is
technically and economically feasible. It provides a reliable optimization
approach for refining and petrochemical enterprises to maximize hydrogen
resource utilization during initial operation stages, which is conducive to the
green and low-carbon development of enterprises.
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Design and
Calculation Method for Insulation Layer Thickness of Petrochemical Equipment
and Pipelines
Zhou Tianyu, Li Jiuchong, Gao Jiansong, Su Yaolun
2026, 43 (3):
25-28.
DOI: 10.3969/j.issn.1005-8168.2026.03.005
When designing and
calculating the insulation layer thickness of petrochemical equipment and
pipelines, the outer diameter of a cylindrical insulation layer can only be
simplified to the implicit function form of D1·ln (D1/D0). However, the methods
of solving for the outer diameter D1 of insulation layer by looking up charts
or manually testing are time-consuming and laborious and has poor accuracy.
Based on four mathematical methods including value-added root seeking method,
bisection method, Monte Carlo method and Newton iteration method, the thickness
of insulation layer can be accurately and efficiently solved combined with the
VBA program or combination of new functions in Excel. In addition, the
characteristics of iteration times and convergence speed of the four
mathematical methods are compared, the selection table for double-layer
insulation thickness is calculated by using Monte Carlo method. This provides
excellent computational support for the thickness design of insulation layer of
petrochemical equipment and pipelines.
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Flow Assurance Analysis and Economic Study on VOCs
Transportation in Multiphase Flow Subsea Pipelines
Zhu Qianwei
2026, 43 (3):
29-36.
DOI: 10.3969/j.issn.1005-8168.2026.03.006
For the extremely complex working
conditions in VOCs transportation in subsea pipelines of a project, such as
gas-liquid multiphase flow, acid corrosion (H?S 1400 ppmv), and large fluctuations
in flow rate (10.35 to 111.32 t/h), this study proposes a coupled optimization
approach that integrates flow assurance simulation with comprehensive economic study.
Based on the multiphase flow simulation using a professional simulation
software, a collaborative analysis on the flow assurance performance and
economic feasibility of VOCs transportation in multiphase flow subsea pipelines
is carried out incorporating third-order flow velocity constraint criteria (gas-phase
flow velocity ≤ 18.3 m/s, inner wall shear stress ≤ 120 Pa, and erosional
velocity ratio EVR < 1.0) and the minimum pressure requirements for pigging (≥
1.0 MPaG). The results indicate that the combined scheme with a compressor
outlet pressure of 1.0 MPaG and a DN500 pipeline offers the most cost-effective
solution while satisfying the process and pigging requirements under acidic
service conditions. This study provides theoretical support and engineering
insights for the systematic optimization of subsea pipelines for VOCs with
condensation phase change.
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Technical Optimization
Measures for Aromatics Extraction Units
Huang Yongfang, Zhai Runhan, Zangshuyan
2026, 43 (3):
37-40.
DOI: 10.3969/j.issn.1005-8168.2026.03.007
This paper introduces the
technical features of the 400 kt/a aromatics extraction unit of a company, and
analyzes its technical optimization potential. By adding the process of
producing C8/C9 mixed aromatics and the process of
producing C7/C8/C9 mixed aromatics, the
processing cost of the unit can be reduced by 1.3182 million yuan and 12.0864
million yuan per year respectively, thus greatly improving the operational
flexibility of the unit and enabling the company to choose appropriate
production mode according to market demands or the principle of maximizing
economic benefits. Two energy saving measures were implemented, including
optimizing the steam consumption structure of the unit and recovering low-temperature
heat from the raffinate extraction tower. Under the main design conditions for
producing three benzene products, the processing cost can be reduced by about 3
million yuan per year. Two suggestions for further work were put forward,
including recovering low-temperature heat from the unit's process condensate
and optimizing the steam consumption structure of aromatics extraction unit in
the refinery area. This research provides guidance and reference for similar
units in refining and petrochemical integration enterprises.
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Energy-saving Optimization of Condensation System of Propylene
Recovery Column in a Propylene Oxide Unit
Li Xinran
2026, 43 (3):
42-47.
DOI: 10.3969/j.issn.1005-8168.2026.03.008/
This paper studies
the condensation system of propylene recovery column in a propylene oxide unit,
compares two process design schemes, and explores the feasibility of
energy-saving optimization paths for the system. Scheme I is a conventional process
flow, consisting of an overhead condenser, a reflux drum, and a discharge pump.
In light of the fact that the overhead stream is mainly composed of propylene
and liquid propylene is required as the refrigerant, the optimized Scheme II is
proposed, which involves installing a compressor at the top of the propylene
recovery column. This scheme increases the dew point temperature through
compression, allows the overhead condenser to use circulating water for
cooling, and installs a reflux drum and a discharge pump to complete the
subsequent material conveying. A detailed comparative calculation of the two
schemes was conducted using ASPEN simulation software. The simulation results
indicate that Scheme II can significantly reduce the load of refrigerant system
and effectively reduce the comprehensive energy consumption of the unit. It is
concluded that Scheme II offers significant energy-saving benefits, providing a
valuable reference for the modification of condensation systems in similar
units.
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Research on LPG Loading Systems
Chen Ruiqi
2026, 43 (3):
48-53.
DOI: 10.3969/j.issn.1005-8168.2026.03.009
An offshore FPSO project carries out separation,
purification and liquefaction processes for natural gas extracted from offshore
sources, so as to produce, store and transport liquefied petroleum gas (LPG)
outward. The FPSO uses ship loading pumps for loading operations. After the
loading is completed, the outgoing pipelines are purged using the overhead gas
from LPG storage tanks. Once the purging is finished, the gaseous and liquid
phase LPG in the system is promptly recovered. This paper examines the purging
and recovery operation of an LPG vapor recovery compressor in the project, introduces
the purging and recovery processes for the outgoing pipelines, and proposes
some measures for ensuring the safe operation of the compressor. HYSYS
simulations are performed to model the outlet temperature of the vaporizer and
calculate the leakage rates under heat exchanger tube rupture scenarios,
providing theoretical guidance for similar LPG loading operations.
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Study on Dynamic Rate Model for Digital Delivery in
Petrochemical Projects
Wang Xiuyun
2026, 43 (3):
54-58.
DOI: 10.3969/j.issn.1005-8168.2026.03.010
Against the background of "dual
carbon" goals, the operation and management of petrochemical enterprises
is undergoing transformation and upgrading from "physical assets" to
the dual-drive of "digital assets + physical assets”. Digital delivery has
gradually become a standard configuration for large-scale projects such as
integrated refining and chemical plants and LNG receiving terminals. However,
there is still a lack of unified definition of the connotation scope,
pricing base and pricing method of digital delivery cost, leading to
frequent disputes during cost estimation, contract negotiation and payment.
Based on a systematic review of the connotation and composition of digital
delivery cost in the petrochemical industry, this paper compares two mainstream
models taking the engineering cost and the basic design and detailed design fee
as the pricing base, respectively. It demonstrates the rationality of using
the basic design and detailed design fee as the pricing base, and proposes
a dynamic rate model of "engineering design correlation coefficient +
multi-dimensional characteristic coefficient + scenario adjustment
coefficient", providing a reference for the quota revision in the
petrochemical industry, the investment decision-making of enterprises, and the bidding
and quotation of engineering companies.
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Application of Digital Delivery Software and Tools in
Telecommunications Field
Huang Wenhao
2026, 43 (3):
59-62.
DOI: 10.3969/j.issn.1005-8168.2026.03.011
This paper introduces the
current status of digital delivery for the telecommunications discipline in
petrochemical projects. Taking AVEVA E3D as an example, it analyzes the
existing problems in the application of the 3D model-centered digital delivery system
in telecommunications engineering. Finally, the 3D modeling software AVEVA E3D
and the database-driven design software EPLAN are respectively adopted to
generate engineering drawings that meet the basic delivery requirements, laying
a research foundation for the further development of digital delivery tools in
the future.
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Practices of Design Quality Improvement for Foreign-funded
Chemical EPC Projects
Ma Zhenming
2026, 43 (3):
63-66.
DOI: 10.3969/j.issn.1005-8168.2026.03.012
During the execution of foreign-funded chemical EPC
projects by domestic engineering companies,
design quality has become one of the key factors determining the success or
failure of projects. Many common problems have emerged in practices, e.g., the design deliverables fail to fully meet the contractual requirements, the process quality management for design documents is lacking, the discipline leads lack overall planning and management
capabilities, inadequate attention is paid to 3D models and digital delivery, and the management and control of project meetings are not given due
emphasis. To address these problems, this paper proposes some systematic solutions, including continuously deepening contract review to integrate the technical requirements into the whole design process to ensure the compliance of deliverables with contractual
terms, prioritizing 3D modeling and multi-disciplinary collaboration to ensure the consistency
between the 3D models and the on-site entities, conducting specialized research on key and difficult issues in project design through thematic discussions and expert evaluations, implementing a form-based mechanism for phased model reviews, and reforming traditional review methods by integrating professional
reviews, information-based inspections and whole process quality supervision to optimize the whole process management. This paper aims to provide practical guidance for improving
design quality management in foreign-funded chemical
EPC projects and help domestic engineering companies enhance their
international market competitiveness.
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Research on Optimization Paths and Countermeasures for
Contract Management of Scientific Research Projects in the Petrochemical
Industry
Liang Yunjie
2026, 43 (3):
67-71.
DOI: 10.3969/j.issn.1005-8168.2026.03.013
Aiming at the widespread problems in contract management of scientific research projects in the petrochemical industry, such as long review cycle, vague definition of rights and responsibilities, and incomplete coverage of risk clauses, this paper proposes an integrated optimization path of "full-cycle risk control embedding + digital dynamic performance". By systematically sorting out the contract characteristics of four types of projects, including in-house independent R&D project, commissioned development project, cooperative R&D project and technical consultation project of enterprises, a system that combines differentiated risk control key points with non-negotiable red line clauses is constructed. Engineering practice shows that relying on lean process management and digital control means, the contract review cycle can be shortened by more than 40%, the technology spillover risk can be reduced by 35%, and the performance dispute rate can be decreased by 50%. This model provides a replicable contract management template for the high-end, intelligent and green transformation of scientific research projects in the petrochemical industry.
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Design and Implementation of Enterprise-level
Intelligent Attendance Management System
Yan Qi
2026, 43 (3):
72-78.
With
the increasing complexity and informatization level of enterprise personnel
management, higher requirements have been put forward for employee attendance
management. Traditional attendance management mostly rely on manual labor and
cannot timely grasp the attendance situation of employees. Data such as leave
and business trip records cannot be linked with attendance in real time,
resulting in more information silos. It is difficult to support efficient
personnel management. Based on BEX5 platform, this article designs and
implements an intelligent, automated and integrated enterprise attendance
management system. The system realizes full process management of leave
application and approval, establishes an intelligent rule engine for complex
office scenarios in multiple locations, provides one click attendance
confirmation management, and automatically forms multi-dimensional comprehensive
statistical report on employee attendance. This system can effectively reduce
human error rates, provide guarantees for improving enterprise management
efficiency and better leveraging personnel value, and help enterprises promote
digital transformation.
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