正己烷 , 丙酮 , 共沸物 , 模拟 ," /> 正己烷 , 丙酮 , 共沸物 , 模拟 ,"/> <p class="MsoNormal" align="left" style="text-align:left;"> <b>萃取精馏分离正己烷<span>-</span>丙酮共沸体系模拟研究<span></span></b>

石油化工设计 ›› 2023, Vol. 40 ›› Issue (4): 42-49.doi: 10.3969/j.issn.1005-8168.2023.04.010

• 配管技术 • 上一篇    下一篇

萃取精馏分离正己烷-丙酮共沸体系模拟研究

白媛媛   

  1. 中国石化工程建设有限公司,北京 100101
  • 收稿日期:2023-03-09 出版日期:2023-11-25 发布日期:2023-11-17
  • 作者简介:白媛媛,女,2016年毕业于天津大学化学工程专业,工学学士,主要从事石油化工设备的设计工作,工程师。电话:010-84876917

Simulation of Separation of N-hexane-acetone Azeotrope by Extractive Distillation

Bai Yuanyuan   

  1. SINOPEC Engineering Incorporation, Beijing, 100101
  • Received:2023-03-09 Online:2023-11-25 Published:2023-11-17

摘要:

采用环己醇、乙二醇甲醚、二甲基亚砜(DMSO)、N-甲基吡咯烷酮(NMP)4种常见溶剂作为萃取剂对正己烷-丙酮共沸体系的萃取精馏过程进行模拟研究,模拟软件选择Aspen Plus V11。采用灵敏度分析工具对连续萃取精馏过程的理论板数、进料位置、溶剂比、回流比等操作参数进行了优化。模拟结果表明:4种溶剂均可作为萃取剂分离正己烷和丙酮共沸物,乙二醇甲醚作为萃取剂时萃取精馏过程所需总能耗最低,且萃取剂回收塔塔釜温度最低,所需热源品位最低。

关键词:

正己烷 ')">"> 正己烷 , 丙酮 , 共沸物 , 模拟

Abstract:

The extractive distillation process of n-hexane-acetone azeotrope was simulated by Aspen plus V11. Four common solvents including cyclohexanol, 2-methoxyethanol, dimethyl sulfoxide (DMSO) and N-methylpyrrolidone (NMP) were selected as the extractant. The operating parameters of continuous extractive distillation such as the number of theoretical plates, feed stage, solvent ratio and reflux ratio were optimized by means of sensitivity analysis tool. The results of simulation show that all the four solvents can separate the n-hexane-acetone azeotrope as the extractants. The total energy consumption of extractive distillation process is the lowest when 2-methoxyethanol is used as the extractant, and the bottom temperature of extractant recovery column is the lowest, so the grade of heat source required is the lowest.