石油化工设计 ›› 2019, Vol. 36 ›› Issue (1): 59-62.doi: 10.3969/j.issn.1005-8168.2019.01.016

• 环保与安全 • 上一篇    下一篇

氨水储罐的火灾和爆炸危险性分析

郑鲜,孙书松,周萍,周寅驰   

  1. 河北寰球工程有限公司,河北 涿州 072754
  • 收稿日期:2018-08-22 接受日期:2018-08-24 出版日期:2019-03-30 发布日期:2019-03-30
  • 通讯作者: 郑鲜,zhengxian@hqcec.com E-mail:zhengxian@hqcec.com
  • 作者简介:郑鲜,女,2000年毕业于河北工业大学化工工艺专业,学士,工程师,主要从事化工工艺设计工作。联系电话:0312-3970972; E-mail: zhengxian@hqcec.com

Hazard Analysis of Fire and Explosion in Ammonia Tank

Zheng Xian, Sun Shusong, Zhou Ping, Zhou Yinchi   

  1. China Huanqiu Contracting & Engineering Corporation (Hebei), Zhuozhou, Hebei, 072754
  • Received:2018-08-22 Accepted:2018-08-24 Online:2019-03-30 Published:2019-03-30
  • Contact: Zheng Xian,zhengxian@hqcec.com E-mail:zhengxian@hqcec.com

摘要: 从常压氨水储罐的气相空间中氨气的体积浓度计算入手,对浓度为10%~30%(摩尔分数)氨水的常压储罐气相空间进行了爆炸危险性分析,指出在环境温度下,氨水储罐上部气体中氨的体积浓度都有可能处于其爆炸极限之间,形成爆炸混合物,此时应按易燃易爆的乙类和防火防爆设计氨水储罐;另外从本质安全考虑,采用氮封措施,使混合气体成为不燃烧、无爆炸危险的物质

关键词: 氨水, 储罐 分压, 体积分数, 爆炸极限

Abstract: The explosion hazard of ammonia (mol.10%~30%) tank is analyzed based on the volume concentration of ammonia in gaseous mixture above the liquid. The results show that the volume concentration of ammonia in gaseous mixture might be between the upper explosion limit and the lower explosion limit at ambient temperature, forming explosive mixture. Ammonia tank shall be designed according to Class B fire and explosion hazard. Considering intrinsic safety, nitrogen sealing measures should be taken to prevent the formation of materials with combustion and explosion hazards

Key words: ammonia, storage tank, partial pressure, volume fraction, explosion limit