石油化工设计 ›› 2026, Vol. 43 ›› Issue (2): 60-66.

• 工程应用 • 上一篇    下一篇

苯乙烯脱色精制单元聚合机理分析及对策研究

刘 亮   

  1. 中韩(武汉)石油化工有限公司

  • 出版日期:2026-05-25 发布日期:2026-05-25
  • 作者简介:刘亮,男,2010年毕业于武汉工程大学化学工程与工艺专业,硕士,工程师,主要从事苯乙烯抽提和裂解汽油加氢装置的工艺和生产管理工作。联系电话:027-86630518,;E-mail:liuliang.zhsh@sinopec.com

Analysis of Polymerization Mechanism in Styrene Decolorization and Purification Unit and the Countermeasure Research

Liu Liang   

  1. Sinopec-SK (Wuhan) Petrochemical Company Limited
  • Online:2026-05-25 Published:2026-05-25

摘要:

为解决苯乙烯抽提装置精制单元易堵塞、运行周期短的问题,本研究以聚合反应机理为基础,系统分析了导致装置关键部位堵塞的主要影响因素,包括工艺温度、脱色剂浓度及反应停留时间等。通过优化脱色剂注入浓度、提升阻聚剂性能及强化工艺参数管控等措施,有效缓解精制系统堵塞现象。实施优化后,装置连续运行周期延长至2a以上,在保持不排放高浓度含盐废水这一环保优势的同时,显著提升了生产稳定性和经济效益。研究表明,基于聚合机理的针对性工艺调控,是保障该绿色脱色技术长期平稳运行的关键。

关键词: 苯乙烯抽提, 聚合机理分析, 优化措施

Abstract:

To address the issues of frequent clogging and short operation cycles in the purification unit of styrene extraction plant, this study systematically analyzed the main factors contributing to the blockage in key components of the unit, including process temperature, decolorizing agent concentration, and reaction residence time, based on polymerization reaction mechanisms. Through measures such as optimizing the injection concentration of the decolorizing agent, improving the performance of polymerization inhibitors, and strengthening the control of process parameters, the clogging in the purification system was effectively mitigated. Following the implementation of these optimizations, the continuous operation cycle of the unit has been extended to over two years. This not only maintains the environmental advantage of avoiding the discharge of high-salinity wastewater, but also significantly enhances production stability and economic benefits. The study demonstrates that targeted process adjustments based on polymerization mechanisms are crucial for ensuring the long-term, stable operation of this green decolorization technology.

Key words: styrene extraction;polymerization mechanism analysis, optimization measure