石油化工设计 ›› 2018, Vol. 35 ›› Issue (4): 72-76.doi: 10.3969/j.issn.1005-8168.2018.04.019

• 环保与安全 • 上一篇    

MBR与Fenton组合工艺处理苯酚丙酮废水的研究

管信佩,王听月   

  1. 天津莱特化工有限公司,天津 300280
  • 收稿日期:2018-03-19 接受日期:2018-04-03 出版日期:2018-11-30 发布日期:2019-05-30
  • 通讯作者: 管信佩,xinpei_guan@163.com E-mail:xinpei_guan@163.com
  • 作者简介:管信佩,男,2011年毕业于江苏南通大学生命科学专业,学士,助理工程师,主要从事废水及油泥处理工艺的技术选择、技术交流,实验室及现场试验、技术工艺包的编制等工作,已获得发明专利3项,实用新型专利1项。联系电话:022-25968918; E-mail: xinpei_guan@163.com

Study on the Treatment of Phenol/Acetone Wastewater by Combined Process of MBR and Fenton

Guan Xinpei, Wang Tingyue   

  1. Littoral Chemical (Tianjin) Co., Ltd., Tianjin, 300280
  • Received:2018-03-19 Accepted:2018-04-03 Online:2018-11-30 Published:2019-05-30
  • Contact: Guan Xinpei,xinpei_guan@163.com E-mail:xinpei_guan@163.com

摘要: 苯酚、丙酮生产装置排放的含酚废水由于具有盐浓度高、有机物浓度高、生物毒性高的特性,是一种成分复杂、较难处理的化工废水。天津莱特化工有限公司根据苯酚丙酮废水的特性筛选驯化得到特效菌种,并且通过MBR(膜化反应器)与Fenton工艺的组合在天津某化工企业对苯酚丙酮废水成功进行了现场中试。在现场中试基础之上,为了达到企业节水减排的要求,对苯酚丙酮废水处理方案进行了优化,将该化工厂乙烯碱渣湿式氧化后的废水及其它生产废水与苯酚丙酮废水混合后在实验室采用MBR与Fenton组合工艺进行了试验,最终处理后的废水COD 小于40 mg/L,氨氮小于2 mg/L,达到地表水环境质量ⅴ类标准

关键词: 苯酚丙酮废水, 特效菌种, 膜生物反应器, Fenton处理技术

Abstract: The phenolic wastewater discharged from phenol and acetone plant is characterized by high salt concentration, high organic concentration and high bio-toxicity. This chemical wastewater has complex composition and is difficult to be treated. According to the characteristics of phenol/acetone wastewater, Littoral Chemical (Tianjin) Co., Ltd. has obtained special bacteria by screening and domesticating. And through the combination of MBR and Fenton technology, a field test of phenol/acetone wastewater was carried out in a chemical enterprise in Tianjin. On the basis of the field test, the treatment scheme for phenol/acetone wastewater was optimized to achieve the water saving and emission reduction goals of the enterprise. After mixing the phenol/acetone wastewater with the spent caustic wastewater from ethylene plant after wet oxidation and other production wastewater, a test was carried out in the laboratory using the combined process of MBR and Fenton. After treatment, the wastewater COD is less than 40mg/L and the ammonia nitrogen is less than 2mg/L, which meet the Grade V environmental quality standard for surface water (GB3838-2002)

Key words: phenol/acetone wastewater, special bacteria, membrane bioreactor/MBR, Fenton processing technology