石油化工设计 ›› 2019, Vol. 36 ›› Issue (1): 5-8.doi: 10.3969/j.issn.1005-8168.2019.01.002

• 设计技术 • 上一篇    下一篇

FHUDS-FZ/SZ组合催化剂在300万t/a国Ⅴ柴油加氢装置上的应用

王建军   

  1. 中国石油化工股份有限公司镇海炼化分公司,浙江 宁波 315207
  • 收稿日期:2018-08-24 接受日期:2018-09-11 出版日期:2019-03-30 发布日期:2019-03-30
  • 通讯作者: 王建军,wangjianj.zhlh@sinopec.com E-mail:wangjianj.zhlh@sinopec.com
  • 作者简介:王建军,男,2010年毕业于辽宁石油化工大学化学工程与工艺专业,工程师,主要从事工艺技术管理工作。联系电话:0574-86445759; E-mail: wangjianj.zhlh@sinopec.com

Application of FHUDS-FZ/SZ Combined Catalyst in 3.0 Mt/a National V Diesel Hydrogenation Unit

Wang Jianjun   

  1. SINOPEC Zhenhai Refining and Chemical Company, Ningbo, Zhejiang, 315207
  • Received:2018-08-24 Accepted:2018-09-11 Online:2019-03-30 Published:2019-03-30
  • Contact: Wang Jianjun,wangjianj.zhlh@sinopec.com E-mail:wangjianj.zhlh@sinopec.com

摘要: 介绍了FHUDS-FZ、FHUDS-SZ组合催化剂在中国石化镇海炼化分公司新建300万t/a柴油加氢装置的应用情况。标定结果表明:以直馏柴油(57.71%)、催化柴油(24.41%)、焦化柴油(17.88%)作为原料,该催化剂(具有较高的脱硫脱氮率)在反应器入口压力8.7 MPa、空速0.8 h-1、平均温度355 ℃、氢油比400:1的工况下,生产的精制柴油硫含量低于8 mg/kg、十六烷值增幅大于4.5、多环芳烃小于7%,完全满足国Ⅴ排放标准。此组合催化剂强度高、抗结焦性能好、稳定性强,可实现装置长周期运行

关键词: FHUDS-FZ, FHUDS- SZ, 组合催化剂, 国ⅴ柴油, 硫含量, 标定

Abstract: The application of FHUDS-FZ and FHUDS-SZ combined catalyst in the new 3.0 Mt/a diesel hydrogenation unit at SINOPEC Zhenhai Refining and Chemical Company is introduced. The unit takes straight run diesel oil (57.71 percent), FCC diesel oil (24.41 percent) and coker diesel oil (17.88 percent) as the raw material, and this catalyst has relatively high desulfurization and denitrification rate. The test run results show that, when the reactor inlet pressure is 8.7 MPa, the space velocity is 0.8h-1, the average temperature is 355℃ and the hydrogen/oil ratio is 400:1, the sulfur content of the refined diesel oil is less than 8 mg/kg, the cetane number is increased by 4.5, and the polycyclic aromatic hydrocarbons are less than 7%,fully meeting the National V emission standards for diesel oil. With high strength, good anti-coking performance and high stability, this combined catalyst can realize long-period operation of the unit

Key words: FHUDS-FZ and FHUDS- SZ combined catalyst, National V diesel, sulfur content, test run