石油化工设计 ›› 2022, Vol. 39 ›› Issue (3): 24-28.doi: 10.3969/j.issn.1005-8168.2022.03.007

• 设计技术 • 上一篇    下一篇

煤化工项目工业尾气综合利用方案浅析

张骏驰  升,刘增岳   

  1. 中国石化长城能源化工有限责任公司,北京  100020
  • 收稿日期:2022-06-21 出版日期:2022-08-25 发布日期:2022-08-30
  • 作者简介:1994毕业于中国石油大学(华东)化学工程专业,首席专家,正高级工程师,主要从事煤化工工艺工作

A Brief Discussion on Comprehensive Utilization Paths of Industrial Exhaust Gas in Coal Chemical Projects

Zhang Junchi, Fu Sheng, Liu Zengyue   

  1. Sinopec Great Wall Energy and Chemical Co., Ltd., Beijing, 100020

  • Received:2022-06-21 Online:2022-08-25 Published:2022-08-30

摘要:

煤经气化制甲醇过程中部分装置尾气中CO和H2组成含量较高,生产企业可作为燃料气用途,也可从中提取H2作为下游装置原料。通过对煤化工企业的甲醇装置尾气组成分析,列出了三种不同尾气利用方案和流程图,计算了不同利用方案的物料平衡及成本构成。通过对不同方案产品产量变化及经济性的详细对比,对不同情况下装置尾气中的热能、CO和H2组分的综合利用途径进行分析。最终提出通过调整工业装置的气相分配方案,可在不新增装置的情况下回收利用工业尾气做燃料气,同时增产了H2,综合看来经济收益较好。

Abstract:

The industrial exhaust gas from some units in coal gasification to methanol process has high CO and H2 contents. Coal chemical enterprises can use such exhaust gas as fuel gas or extract H2 as raw material for downstream units. By analyzing the composition of exhaust gas from methanol plants in coal chemical enterprises, this paper proposes three different exhaust gas utilization schemes and flow charts, and calculates the material balance and cost structure of these schemes. With a detailed comparison of the product output changes and economic efficiency of different schemes, the comprehensive utilization paths of heat energy, CO and H2 components in the exhaust gas under different conditions are analyzed. The scheme of adjusting the gas phase distribution can recycle the industrial exhaust gas as fuel gas without adding new units and increase the production of H2, achieving good economic benefits.